Nagoya University-led international collaboration develops new approach to advanced sensor and energy harvesting devices based on controlling domain alignment in nanostructured ferroelectric materials.
press released on 28, 2017
Caption: Charge screening in ferroelectric Pb(Zr,Ti)O3 nanorods was used to control their domain pattern. The c-domain fraction markedly increased with as the rod width decreased, while the a-domain formation prevailed by metallization of their sidewall. All the observed results could be explained by the depolarizing field, arising from the imperfect charge screening. This approach could be expanded to other low-dimensional nanoscale ferroelectric systems. © Tomoaki Yamada
Nagoya, Japan － Many next-generation electronic and electro-mechanical device technologies hinge on the development of ferroelectric materials. The unusual crystal structures of these materials have regions in their lattice, or domains, that behave like molecular switches. The alignment of a domain can be toggled by an electric field, which changes the position of atoms in the crystal and switches the polarization direction. These crystals are typically grown on supporting substrates that help to define and organize the behavior of domains. Control over the switching of domains when making crystals of ferroelectric materials is essential for any future applications.
Now an international team by Nagoya University has developed a new way of controlling the domain structure of ferroelectric materials, which could accelerate development of future electronic and electro-mechanical devices.
"We grew lead zirconate titanate films on different substrate types to induce different kinds of physical strain, and then selectively etched parts of the films to create nanorods," says lead author Tomoaki Yamada. "The domain structure of the nanorods was almost completely flipped compared with [that of] the thin film."
Lead zirconate titanate is a common type of ferroelectric material, which switches based on the movement of trapped lead atoms between two stable positions in the crystal lattice. Parts of the film were deliberately removed to leave freestanding rods on the substrates. The team then used synchrotron X-ray radiation to probe the domain structure of individual rods.
The contact area of the rods with the substrate was greatly reduced and the domain properties were influenced more by the surrounding environment, which mixed up the domain structure. The team found that coating the rods with a metal could screen the effects of the air and they tended to recover the original domain structure, as determined by the substrate.
"There are few effective ways of manipulating the domain structure of ferroelectric materials, and this becomes more difficult when the material is nanostructured and the contact area with the substrate is small." says collaborator Nava Setter. "We have learned that it's possible to nanostructure these materials with control over their domains, which is an essential step towards the new functional nanoscale devices promised by these materials."
The article, "Charge screening strategy for domain pattern control in nanoscale ferroelectric systems," was published in Scientific Reports at DOI:10.1038/s41598-017-05475-x
Authors: Tomoaki Yamada 1,2, Daisuke Ito1, Tomas Sluka 3, Osami Sakata 4,5, Hidenori Tanaka 5, Hiroshi Funakubo 5, Takahiro Namazu 6, Naoki Wakiya 7, Masahito Yoshino 1, Takanori Nagasaki 1 & Nava Setter 3,8
1 Department of Materials, Physics and Energy Engineering, Nagoya University
2 PRESTO,Japan Science and Technology Agency
3 Ceramics Laboratory, EPFL - Swiss Federal Institute of Technology
4 Synchrotron X-ray Station at SPring-8 and Synchrotron X-ray Group, National Institute for Materials Science
5 School of Materials and Chemical Technology, Tokyo Institute of Technology
6 Department of Mechanical Engineering, Aichi Institute of Technology
7 Research Institute of Electronics, Shizuoka University
8 Department of Materials Science and Engineering, Tel-Aviv University
Energy-related Materials Research Group, Department of Energy Engineering/ Department of Materials, Physics and Energy Engineering, Graduate School of Engineering, Nagoya University
Tomoaki Yamada, research theme; Piezoelectric Oblique Nanostructures for Smart Sensing, research area/ project; Nanosystems and Emergent Functions, PRESTO, JST
Tomoaki Yamada, research theme; Piezoelectric Films with Enhanced Response by Polarization Manipulation, research area/project; Scientific Innovation for Energy Harvesting Technology, PRESTO, JST
Funding: This work was mainly supported by JST-PRESTO "Nanosystems and Emergent Functions" and "Scientific Innovation for Energy Harvesting Technology, Grant No. JPMJPR16R9" (TY), and partially supported by the JSPS KAKENHI Grant No. 26709047 (TY), 15K13944 (TY), 18310085 (OS), 26220907 (HF) and 15H04121(HF), and JST Concert-Japan Project "FF-Photon" (TY and NW).